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2D/2d heterojunction of MoS2/g-C3N4 nanoflowers for enhanced visible-light-driven photocatalytic and electrochemical degradation of organic pollutants.
- Source :
-
Journal of Environmental Management . Nov2020, Vol. 274, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- Photodegradation of toxic pollutants is a promising approach to deal with wastewater management. In this regard, MoS 2 /g-C 3 N 4 (MSC) derived composites with varying weight-ratios were prepared via fast (30 min) one step microwave-assisted method. The materials were characterized by XRD, XPS, EDS, FESEM and HRTEM to validate their flower-like and sheet-like morphologies. The PL and UV–vis DRS spectra exhibited low recombination-rate and band-gap (1.7 eV), which is appropriate for an effective visible-light degradation. Photocatalytic performance of the catalysts was analyzed by investigating the degradation of methylene blue (MB) as well as pesticide fipronil. Best results were obtained by 5:1 MSC (98.7% degradation efficacy; rate constant 0.0261 min−1) in 80 min under the sunlight. The effects of solution pH, catalyst-dose, scavengers and illumination-area were also explored. The catalyst was reusable as confirmed by degradation studies (~82% efficiency) even after 5-cycles. The photocatalytic treatment of real industrial-wastewater was also conducted. The TOC and COD analysis validated that the treatment by as-prepared catalyst is more proficient for effluent-treatment than the industrial physico-chemical treatments. Electrochemical degradation of MB was also investigated using the glassy carbon electrode modified with different MSC-ratios. The electrode modified with 5:1 MSC at pH 7 manifested the maximum peak current. The plausible mechanisms for photocatalytic and electrochemical degradations were proposed, which suggested the remarkable potential the prepared nanocomposites for wastewater treatment. Image 1 • MoS 2 /g-C 3 N 4 composites with different weight ratio were synthesized by microwave method. • Visible light active nanocomposites are highly effective for toxic pollutant degradation. • Degradation efficiency was remarkably affected by the amount of MoS 2 and g-C 3 N 4. • Electrochemical degradation of MB was studied using MoS 2 /g-C 3 N 4 modified GCE. • COD and TOC analysis of real wastewater confirm the efficiency of the catalysts. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03014797
- Volume :
- 274
- Database :
- Academic Search Index
- Journal :
- Journal of Environmental Management
- Publication Type :
- Academic Journal
- Accession number :
- 145994331
- Full Text :
- https://doi.org/10.1016/j.jenvman.2020.111208