Chiral Dinuclear Benzyliminobinaphthoxy‐Palladium Catalyst for Asymmetric Mannich Reaction of Aldimines and Isatin‐Derived Ketimines with Alkylmalononitriles.

Authors :: Nakamura, Ayu
Kuwano, Satoru
Sun, Junchuan
Araseki, Kensuke
Ogino, Eri
Arai, Takayoshi
Source :: Advanced Synthesis & Catalysis. 8/4/2020, Vol. 362 Issue 15, p3105-3109. 5p.
Publication Year :: 2020
Abstract: A newly developed dinuclear bis(benzylimino)binaphthol (BIB)−Pd complex showed good catalytic activity for the Mannich reaction of aldimines and isatin‐derived ketimines with alkylmalononitriles to give the products in a highly enantioselective manner. [ABSTRACT FROM AUTHOR]

Subjects :: *MANNICH reaction
*IMINES
*ALDIMINES
*CATALYSTS
*CATALYTIC activity

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