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The Exceptional Diversity of Homoleptic Uranium–Methyl Complexes.
- Source :
-
Angewandte Chemie International Edition . 8/3/2020, Vol. 59 Issue 32, p13586-13590. 5p. - Publication Year :
- 2020
-
Abstract
- Homoleptic σ‐bonded uranium–alkyl complexes have been a synthetic target since the Manhattan Project. The current study describes the synthesis and characterization of several unprecedented uranium–methyl complexes. Amongst these complexes, the first example of a homoleptic uranium–alkyl dimer, [Li(THF)4]2[U2(CH3)10], as well as a seven‐coordinate uranium–methyl monomer, {Li(OEt2)Li(OEt2)2UMe7Li}n were both crystallographically identified. The diversity of complexes reported herein provides critical insight into the structural diversity, electronic structure and bonding in uranium–alkyl chemistry. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 59
- Issue :
- 32
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 144868873
- Full Text :
- https://doi.org/10.1002/anie.202005138