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Indium (I) Iodide-Promoted Cleavage of Diaryl Diselenides and Disulfides and Subsequent Condensation with Alkyl or Acyl Halides. One-Pot Efficient Synthesis of Diorganyl.

Authors :
Ranu, Brindaban C.
Mandal, Tanmay
Source :
Journal of Organic Chemistry. 8/20/2004, Vol. 69 Issue 17, p5793-5795. 3p. 1 Chart.
Publication Year :
2004

Abstract

Diphenyl diselenides and disulfides undergo facile cleavages by indium(I) iodide and the corresponding generated selenate and thiolate anions condense in situ with alkyl or acyl halides present in the reaction mixture. Thus, a simple, efficient, and general procedure has been developed for the synthesis of unsymmetrical diorganyl selenides, sulfides (thioethers), selenoesters, and thioesters by this one-pot reaction at room temperature. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00223263
Volume :
69
Issue :
17
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
14379993
Full Text :
https://doi.org/10.1021/jo0493727