Back to Search
Start Over
Indium (I) Iodide-Promoted Cleavage of Diaryl Diselenides and Disulfides and Subsequent Condensation with Alkyl or Acyl Halides. One-Pot Efficient Synthesis of Diorganyl.
- Source :
-
Journal of Organic Chemistry . 8/20/2004, Vol. 69 Issue 17, p5793-5795. 3p. 1 Chart. - Publication Year :
- 2004
-
Abstract
- Diphenyl diselenides and disulfides undergo facile cleavages by indium(I) iodide and the corresponding generated selenate and thiolate anions condense in situ with alkyl or acyl halides present in the reaction mixture. Thus, a simple, efficient, and general procedure has been developed for the synthesis of unsymmetrical diorganyl selenides, sulfides (thioethers), selenoesters, and thioesters by this one-pot reaction at room temperature. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 69
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 14379993
- Full Text :
- https://doi.org/10.1021/jo0493727