Thermal and optical characterization of multiple hydrogen bonded liquid crystals derived from mesogenic and non-mesogenic compounds: experimental and theoretical (DFT) studies.

A set of new cyclic multiple hydrogen bonded liquid crystals (HBLCs) have been designed and synthesized from citric acid (CA) and 4-dodecyloxybenzoic acid (12OBA). The presence of intermolecular hydrogen bonds (H-bonds) between non-mesogenic and mesogenic compounds has been confirmed by Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopy and density functional theory (DFT) studies. The hydrogen bonding interactions were explained from natural bond orbital (NBO) analysis using B3LYP/6-311G(d,p) level of theory. Additionally, the Mulliken atomic charges reveal the nature of charge distribution in the HBLC complex. The dynamics of phase transitions and the corresponding stability factor have been evaluated using polarizing optical microscopy (POM), differential scanning calorimetry (DSC), and electrostatic potential (ESP) analysis. Highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies of the CA+12OBA complex is theoretically calculated and experimentally verified. It is found that the variation in the mole ratio in mesogenic with non-mesogenic compound induces the stabilized nematic (N) and smectic X (Sm X) phases. Photocatalytic activity of the CA+12OBA HBLC complex reveals the usage of its optical applications. [ABSTRACT FROM AUTHOR]