Back to Search
Start Over
Lewis acid capping of a uranium(V) nitride via a uranium(III) azide molecular square.
- Source :
-
Chemical Communications . 4/28/2020, Vol. 56 Issue 33, p4535-4538. 4p. - Publication Year :
- 2020
-
Abstract
- Reaction of (CpiPr4)2UI with NaN3 resulted in formation of tetrameric uranium(III) azide-bridged 'molecular square' [(CpiPr4)2U(μ-η1:η1-N3)]4 (1). Addition of B(C6F5)3 to 1 induced loss of N2 at room temperature, yielding the uranium(V) borane-capped nitrido (CpiPr4)2U(μ-N)B(C6F5)3 (2). [ABSTRACT FROM AUTHOR]
- Subjects :
- *URANIUM
*LEWIS acids
*URANIUM oxides
*NITRIDES
*URANIUM compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 142873036
- Full Text :
- https://doi.org/10.1039/d0cc01356k