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Photoinduced ligand dissociation follows reverse energy gap law: nitrile photodissociation from low energy 3MLCT excited states.
- Source :
-
Chemical Communications . 4/14/2020, Vol. 56 Issue 29, p4070-4073. 4p. - Publication Year :
- 2020
-
Abstract
- A series of Ru(II)-terpyridine complexes containing electron-donating bidentate ligands are able to effectively photodissociate nitrile ligands using red light. A spectroscopic investigation of these complexes reveal that they follow anti-energy gap law behavior, providing further evidence that population of 3LF excited states is not necessary for photoinduced nitrile dissociation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BAND gaps
*PHOTODISSOCIATION
*LIGANDS (Chemistry)
*INVESTIGATIONS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 29
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 142652309
- Full Text :
- https://doi.org/10.1039/c9cc10095d