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1,3-Carboboration of iodonium ylides.
- Source :
-
Chemical Communications . 3/18/2020, Vol. 56 Issue 22, p3345-3348. 4p. - Publication Year :
- 2020
-
Abstract
- Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage. [ABSTRACT FROM AUTHOR]
- Subjects :
- *YLIDES
*MANUFACTURED products
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 142295025
- Full Text :
- https://doi.org/10.1039/c9cc08749d