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Alkali metal reduction of 1,3,2-diazaborol and 1,3,2-diazagermol derivatives based on 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 3/7/2020, Vol. 49 Issue 9, p2941-2946. 6p. - Publication Year :
- 2020
-
Abstract
- The reduction of [(dpp-bian)BBr] (1, dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with dilithium naphthalenide in Et2O gives [{(dpp-bian)BBr}Li2(Et2O)2]2 (3). The treatment of [(dpp-bian)BONa] (5) and [(dpp-bian)Ge:] (7) with sodium is accompanied by protonation of the acenaphthylene fragment and affords [{(H-dpp-bian)BONa(dme)2}Na(dme)3] (6) and [(H-dpp-bian)Ge:][Na(dme)3] (8), respectively. Compounds 3, 6 and 8 have been characterized by 1H NMR and IR spectroscopy. The molecular structures of 3, [(dpp-bian)BOK] (4) and 8 have been established by single crystal X-ray analysis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 49
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 142040105
- Full Text :
- https://doi.org/10.1039/c9dt04652f