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Tuning morphology and structure of Fe–N–C catalyst for ultra-high oxygen reduction reaction activity.
- Source :
-
International Journal of Hydrogen Energy . Feb2020, Vol. 45 Issue 11, p6380-6390. 11p. - Publication Year :
- 2020
-
Abstract
- Exploring efficient and durable non-precious metal catalysts for oxygen reduction reaction (ORR) has long been pursued in the field of metal-air batteries, fuel cells, and solar cells. Rational design and controllable synthesis of desirable catalysts are still a great challenge. In this work, a novel approach is developed to tune the morphologies and structures of Fe–N–C catalysts in combination with the dual nitrogen-containing carbon precursors and the gas-foaming agent. The tailored Fe–N 1 /N 2 –C-A catalyst presents gauze-like porous nanosheets with uniformly dispersed tiny nanoparticles. Such architectures exhibit abundant Fe-N x active sites and high-exposure surfaces. The Fe–N 1 /N 2 –C-A catalyst shows extremely high half-wave potential (E 1/2 , 0.916 V vs. RHE) and large limiting current density (6.3 mA cm−2), far beyond 20 wt% Pt/C catalyst for ORR. This work provides a facile morphological and structural regulation to increase the number and exposure of Fe-N x active sites. The tailored Fe–N–C catalyst presents plentiful Fe-N x active sites and highly exposed active surfaces, resulting in an ultra-high ORR activity far beyond the 20 wt% Pt/C catalyst. Image 1 • A novel approach is explored to tune morphology and structure of Fe–N–C catalyst. • The tailored catalyst presents abundant active sites and high exposure surfaces. • The catalyst shows ultrahigh ORR activity, far beyond the commercial Pt/C. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 45
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 141810442
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2019.12.130