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Reliable and selective lead-ion sensor of sulfur-doped graphitic carbon nitride nanoflakes.
- Source :
-
Applied Surface Science . Mar2020, Vol. 506, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- • S-g-C 3 N 4 nanoflake with a large specific surface area of 189.26 m2 g−1 was prepared. • The proposed S-g-C 3 N 4 /GCE sensor exhibited excellent performance for Pb2+ detection. • The high selectivity can be attributed to a strong interaction via S Pb bond. • The strong interaction between S-g-C 3 N 4 interface and Pb2+ was confirmed by DFT. An optimum large specific surface area of sulfur-doped graphitic carbon nitride nanoflakes modified glassy carbon electrode (S-g-C 3 N 4 /GCE) is reported with promising lead ion (Pb2+) detection capability. This sensor was designed and fabricated using thermal polycondesation reaction. In terms of high selectivity Pb2+ performance, we noted that the sensor exhibited appreciable detection limit of 3.0 × 10−9 mol L−1 (S/N = 3) within the ionic specimen concentration range of 7.5 × 10−8 ~ 2.5 × 10−6 mol L−1 and 2.5 × 10−6 ~ 1 × 10−3 mol L−1. Corroborated by DFT calculations, we propose that the strong interaction of S-g-C 3 N 4 interface and Pb2+ plays an important role to generate the aforementioned sensing characteristics. In practice, we conceived high detection of Pb2+ ions that reside in lake-water and mineral samples in which percentage recovery of 88–103 can be obtained under high repetition rate. Thus, S-g-C 3 N 4 /GCE can be considered as sensitive and selective electrochemical sensor for a reliable detecting heavy metal ions in domestic sewage and industrial wastewater. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 506
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 141631272
- Full Text :
- https://doi.org/10.1016/j.apsusc.2019.144672