Anti-sintering Pd@silicalite-1 for methane combustion: Effects of the moisture and SO2.

Sintering and sulfur poisoning are the causes of the deactivation of most catalysts. Herein, the Pd clusters were encapsulated into the all-silica zeolite by one-step synthesis to obtain a core-shell structure (denoted as Pd@S-1) for catalytic combustion of methane with good catalytic activity and high stability. Under the harsh conditions such as 800 °C aging for 10 h, 10% water vapor aging for 100 h and 100 ppm SO 2 poisoning for 15 h, the Pd particles are prevented from migration and growth due to the confinement of the S-1 shell layer. As comparison, Pd/S-1 and Pd 0.8 Ni 0.2 /S-1 sample have different degrees of sintering, resulting in partial deactivation. For Pd 0.8 Ni 0.2 @S-1 sample, the introduction of Ni not only enhances the catalytic activity, but also improves the thermal stability. However, the moisture and sulfur resistance of Pd 0.8 Ni 0.2 @S-1 catalyst is much lower than that of Pd@S-1 catalyst. A series of characterizations show that the S-1 shell has a shielding effect for SO 2. We proposed that the formation of large-sized PdSO 4 clusters is prevented due to the confinement effect of S-1 micropore, resulting in SO 2 easily desorbed on Pd@S-1 surface, which significantly lowers the temperature of Pd@S-1 catalyst regeneration. Unlabelled Image • The confinement effect of the S-1 shell prevents the growth of Pd nanoparticles. • The Pd 0.8 Ni 0.2 @S-1 catalyst does not undergo severe sintering at 900 °C for 5 h with the T 90 = 425 °C. • Even under 450 °C, 10% water vapor for 100 h, the Pd particle size on the Pd@S-1 remains unchanged. • The sulfur-poisoned Pd@S-1 catalyst can recover its catalytic activity under lean-burn conditions. [ABSTRACT FROM AUTHOR]