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Direct conversion of uranium dioxide UO2 to uranium tetrafluoride UF4 using the fluorinated ionic liquid [Bmim][PF6].

Authors :
Joly, Florian
Simon, Pardis
Trivelli, Xavier
Arab, Mehdi
Morel, Bertrand
Solari, Pier Lorenzo
Paul, Jean-Francois
Moisy, Philippe
Volkringer, Christophe
Source :
Dalton Transactions: An International Journal of Inorganic Chemistry. 1/14/2020, Vol. 49 Issue 2, p274-278. 5p.
Publication Year :
2020

Abstract

The industrial fluorination of UO2 to UF4 is based on a complex process involving the manipulation of a large amount of HF, a very toxic and corrosive gas. We present here a safer way to accomplish this reaction utilizing ionic liquid [Bmim][PF6] as a unique reaction medium and fluoride source. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14779226
Volume :
49
Issue :
2
Database :
Academic Search Index
Journal :
Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
141010943
Full Text :
https://doi.org/10.1039/c9dt04327f