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High-performance solid-state bendable supercapacitors based on PEGBEM-g-PAEMA graft copolymer electrolyte.
- Source :
-
Chemical Engineering Journal . Mar2020, Vol. 384, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- • PEGBEM-g-PAEMA graft copolymer is synthesized via free-radical polymerization. • The electrolyte maintained its flexible solid film state for EMIMBF 4 content up to 200%. • The solid capacitors exhibited good bending performance without specific encapsulation. • The capacitors with PEGBEM-g-PAEMA exhibited better performance compared with other polymer/EMIMBF 4 cells. We report a solid electrolyte comprising poly(ethylene glycol) behenyl ether methacrylate-g-poly((2-acetoacetoxy)ethyl methacrylate) (PEGBEM-g-PAEMA) graft copolymer for application to solid-state bendable supercapacitors. The graft copolymer was synthesized via free-radical polymerization, and the electrolytes were fabricated by adding 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF 4). Fourier-transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, X-ray diffraction, small-angle X-ray scattering, and transmission electron microscopy were employed to investigate the chemical, structural, thermal, and morphological properties of the fabricated electrolytes and the compatibility of the two components. The graft copolymer interacted with EMIMBF 4 (the two materials were compatible with each other), and the intruded ionic liquid was well-dispersed through the entire region of the polymer matrix. The fabricated electrolyte maintained its flexible solid film state for EMIMBF 4 content up to 200% without leakage problems. The capacitors were manufactured with porous carbon electrodes and a PEGBEM-g-PAEMA/EMIMBF 4 electrolyte. The capacitors exhibited a capacitance of 55.5F/g, a power density of 900 W/kg, and an energy density of 25 Wh/kg at 1.0 A/g. The capacitors were measured at various bending angles and exhibited good performance without specific encapsulation. According to the results, the newly synthesized PEGBEM-g-PAEMA graft copolymer is a good candidate for a polymer matrix for electrolytes in all-solid-state bendable/flexible supercapacitors. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 384
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 140846929
- Full Text :
- https://doi.org/10.1016/j.cej.2019.123308