Utilization of Sodium Hexametaphosphate for Separating Scheelite from Calcite and Fluorite Using an Anionic–Nonionic Collector.

This study presents a highly selective reagent system that utilizes sodium hexametaphosphate (SHMP) to improve the separation of scheelite from calcite and fluorite using an anionic–nonionic collector. The recoveries of calcite and fluorite decreased to 20% as the SHMP dose exceeded 6 × 10−6 mol/L, whereas that of scheelite remained at 85%. The interaction mechanisms of minerals with SHMP were investigated through equilibrium speciation, Zeta potential, Fourier transform infrared spectrometry, and X-ray photoelectron spectroscopy analyses. SHMP exists as hydrogen phosphate anion in the aqueous solution with a pH of 7–12. Moreover, it may be adsorbed intensively on the positively charged surfaces of calcite and fluorite via electrostatic force or chelation with calcium ion to impede further adsorption of the assembled collector. By comparison, the adsorption of SHMP is feeble on the scheelite surface because of its negative charge. The roughing grade of low-grade scheelite ore is substantially improved from 0.74% to 1.65% compared with that in the contrast test in the absence of SHMP. [ABSTRACT FROM AUTHOR]