Promoting dimethyl ether carbonylation over hot-water pretreated H-mordenite.

• The hot-water pretreatment can generate new Brønsted acid sites. • The hot-water pretreated H-MOR shows high activity for DME carbonylation. • The hot-water pretreated H-MOR accelerates the formation of methoxy groups. • The residue water molecules will inhibit DME carbonylation. Herein, we report the effect of the hot-water pretreatment on the catalytic activity of the H-mordenite (H-MOR) zeolite for DME carbonylation. The structure and acidity of the H-MOR catalysts pretreated by hot water were systematically characterized by XRD, nitrogen adsorption, SEM, H 2 O-TPD, NH 3 -TPD, 1H NMR and NH 3 -DRIFTS technologies. With the increase of the duration of the hot-water pretreatment, the catalytic activity shows a volcano-type variation. The H-MOR catalyst pretreated by hot water for 10 min at 573 K displays the highest catalytic activity among all of the catalysts. The appropriate duration of the hot-water pretreatment can generate new medium strong and strong Brønsted acid sites, which changes the microenvironment in the pores of H-MOR. Additionally, the newly generated Brønsted acid sites will accelerate the first step of DME carbonylation, that is, DME reacts with the Brønsted acid sites of the zeolite forming surface methoxy groups and methanol, improving the catalytic activity of the catalysts. However, too long duration of the hot-water pretreatment will remain water molecules in H-MOR, which inhibits DME carbonylation. [ABSTRACT FROM AUTHOR]