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Li4Ti5O12/TiO2 dual-phase anode materials synthesized in supercritical water-methanol system and investigations on its superior electrochemical performance for lithium-ion batteries.
- Source :
-
Journal of Supercritical Fluids . Dec2019, Vol. 154, pN.PAG-N.PAG. 1p. - Publication Year :
- 2019
-
Abstract
- • Supercritical water-methanol mixture was used as reaction media. • Li 4 Ti 5 O 12 /TiO 2 dual-phase composite showed superior electrochemical properties. • Oxygen vacancy: an important role in enhancing electrochemical performance. • Pseudocapacitive effect in Li 4 Ti 5 O 12 /TiO 2 was pivotal. Li 4 Ti 5 O 12 /TiO 2 dual-phase composite compound is prepared through a supercritical fluid process with the mixture of water and methanol as solvothermal reaction media (380 °C and 31.5 MPa). When employed as anode material for lithium-ion batteries, the newly synthesized Li 4 Ti 5 O 12 /TiO 2 composite exhibits a high initial discharge capacity of 191 mA h g−1 at a current density of 100 mA g−1, and delivers a capacity retention of 90.7% even after 500 cycles at 1000 mA g−1 with the voltage window of (1.0–2.5)V. The enhanced electrochemical performance is attributed to the oxygen vacancies, the phase grain boundaries and reduced size of the Li 4 Ti 5 O 12 /TiO 2 composite particles. In addition, pseudocapacitive effect for the superior electrochemical performance of Li 4 Ti 5 O 12 /TiO 2 dual-phase composite is investigated in detail. The carbon-free Li 4 Ti 5 O 12 /TiO 2 dual-phase composite with high safety would be a promising candidate for applications in high-power lithium ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08968446
- Volume :
- 154
- Database :
- Academic Search Index
- Journal :
- Journal of Supercritical Fluids
- Publication Type :
- Academic Journal
- Accession number :
- 139030403
- Full Text :
- https://doi.org/10.1016/j.supflu.2019.104596