Frontispiece: Synthetic Diversity from a Versatile and Radical Nitrating Reagent.

Keywords: alkenes; C-H nitration; photoredox; radicals; reaction mechanisms Furthermore, using in situ photo-sensitized, electron paramagnetic resonance spectroscopy, clear evidence for a nitryl radical in solution by nitrone spin-trapping was obtained. Alkenes, C-H nitration, photoredox, radicals, reaction mechanisms. [Extracted from the article]