Dynamics of nitrate degradation along an alternative latrine improved by a sawdust permeable reactive barrier (PRB) installed in an irregular settlement in the municipality of São Paulo (Brazil).

• Control latrine played a typical geochemical behavior of a contaminant source. • Alternative latrine oxidized almost completely ammonium to nitrate. • Nitrate removal efficiency promoted by sawdust layer was of 42% on average. • Isotopes analyses corroborated N-species hydrogeochemistry trends across latrines. • Relative placement of sawdust and BOF slag layers impacted denitrifiers performance. Nutrients, like nitrate and phosphate, and pathogens are the primary contaminants released into groundwater by on-site sanitation systems, which are an effluent disposal outcome for regions not covered by sanitation infrastructure, as periurban communities in developing countries. As appropriate setback distances between pit latrines and supply wells often cannot be met to avoid groundwater contamination, especially in a densely-populated situation, efficient, low-cost and accessible technologies are extremely necessary to protect water resources and surpass critical and persistent public health problems. This paper presents 1-year field-testing of an alternative latrine (AL) that incorporates two waste materials as permeable reactive barriers (PRB) in an irregular settlement at the municipality of São Paulo (Brazil). Basic oxygen furnace (BOF) slag in contact with wastewater effluent increases its pH level, which causes pathogens inactivation and phosphate adsorption. Sawdust under water saturation creates reducing conditions that encourage the growth of denitrifying bacteria that remove nitrate. A control latrine (CL) was constructed 90 m apart from AL with similar hydraulic characteristics and nonreactive materials for hydrochemical comparison. It was evident for AL the formation of well-defined nitrification and denitrification reaction zones, whereas CL overall presented nitrogen in its ammoniacal form, with incipient nitrate production at CL bottom, indicating that nitrification is probably boosted below that. BOF slag had attenuated microorganisms and phosphate almost completely, but nitrate removal average efficiency was 42%. The high pH effluent generated in BOF media may have also affected in the short-term the denitrifying bacteria in sawdust barrier 1 m below. The inverted position of the reactive barriers, i.e., sawdust PRB overlying BOF slag PRB, should be a more suitable design to achieve nitrate and pathogens removal. This kind of sanitation solution employing cheap and accessible waste materials have never been applied in the design proposed in this paper and also was a novelty for Brazilian context, proving to be a suitable technology to meet local needs. [ABSTRACT FROM AUTHOR]