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Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride.

Authors :
Han, Hye Jin
Oh, Ju Hyun
Sessler, Jonathan L.
Kim, Sung Kuk
Source :
Chemical Communications. 9/18/2019, Vol. 55 Issue 73, p10876-10879. 4p.
Publication Year :
2019

Abstract

A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride anion within its cavity even after one or two pyrrolic NH protons were subject to deprotonation. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
55
Issue :
73
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
138522152
Full Text :
https://doi.org/10.1039/c9cc05613k