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Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride.
- Source :
-
Chemical Communications . 9/18/2019, Vol. 55 Issue 73, p10876-10879. 4p. - Publication Year :
- 2019
-
Abstract
- A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride anion within its cavity even after one or two pyrrolic NH protons were subject to deprotonation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DETECTION limit
*PROTON transfer reactions
*FLUORIDES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 73
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 138522152
- Full Text :
- https://doi.org/10.1039/c9cc05613k