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Oxygen-vacancy-rich nickel-cobalt layered double hydroxide electrode for high-performance supercapacitors.
- Source :
-
Journal of Colloid & Interface Science . Oct2019, Vol. 554, p59-65. 7p. - Publication Year :
- 2019
-
Abstract
- The introduction of oxygen vacancies into electrode materials has been proven to be a valid way to enhance the electrochemical performance. However, the traditional methods to introduce oxygen vacancies require severe conditions that may be harmful to hydroxides. Herein, the oxygen vacancy-rich nickel-cobalt (NiCo) layered double hydroxide (denoted as V o -NiCo LDH) nanowire array electrode is synthesized using the chemical reduction method. Owing to the reduction of NaBH 4 solution, we can create oxygen vacancies under milder conditions, thus avoiding any damage to the hydroxide. The as-synthesized electrode shows a specific capacitance of 1563.1 F g−1 at 1 A g−1, which is much higher than that of the pristine electrode (995.4 F g−1 at 1 A g−1). Moreover, the cycling performance and rate performance are also enhanced. The as-fabricated asymmetric supercapacitor (V o -NiCo LDH//Fe 2 O 3) is able to deliver a maximum energy density of 56.2 W h kg−1 at a power density of 800 W kg−1 with a voltage window of 1.6 V. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219797
- Volume :
- 554
- Database :
- Academic Search Index
- Journal :
- Journal of Colloid & Interface Science
- Publication Type :
- Academic Journal
- Accession number :
- 138479309
- Full Text :
- https://doi.org/10.1016/j.jcis.2019.06.095