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Mn(I)-Catalyzed nucleophilic addition/ring expansion via C–H activation and C–C cleavage.
- Source :
-
Chemical Communications . 9/16/2019, Vol. 55 Issue 72, p10764-10767. 4p. - Publication Year :
- 2019
-
Abstract
- Mn(I)-Catalyzed synthesis of seven- or eight-membered carbocycles is disclosed via C–H activation of heteroarenes and coupling with alkyne-functionalized 1,3-cyclopentadiones or 1,3-cyclohexadiones. This n to n + 2 (n = 5, 6) ring expansion reaction proceeded via a C–H alkenylation/carbonyl addition/retro-Aldol cascade. Structurally diverse mid-sized carbocycles were constructed via cleavage of both C–H and C–C bonds in a single operation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENYLATION
*RING-opening reactions
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 72
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 138442816
- Full Text :
- https://doi.org/10.1039/c9cc05973c