σ‐Noninnocence: Masked Phenyl‐Cation Transfer at Formal NiIV.

Reductive elimination is an elementary organometallic reaction step involving a formal oxidation state change of −2 at a transition‐metal center. For a series of formal high‐valent NiIV complexes, aryl–CF3 bond‐forming reductive elimination was reported to occur readily (Bour et al. J. Am. Chem. Soc. 2015, 137, 8034–8037). We report a computational analysis of this reaction and find that, unexpectedly, the formal NiIV centers are better described as approaching a +II oxidation state, originating from highly covalent metal–ligand bonds, a phenomenon attributable to σ‐noninnocence. A direct consequence is that the elimination of aryl–CF3 products occurs in an essentially redox‐neutral fashion, as opposed to a reductive elimination. This is supported by an electron flow analysis which shows that an anionic CF3 group is transferred to an electrophilic aryl group. The uncovered role of σ‐noninnocence in metal–ligand bonding, and of an essentially redox‐neutral elimination as an elementary organometallic reaction step, may constitute concepts of broad relevance to organometallic chemistry. [ABSTRACT FROM AUTHOR]