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Synthesis and optical temperature sensing performance of NaLa(MoO4)2: Tb3+, Eu3+ phosphors.

Authors :
Peng, Lixin
Meng, Qingyu
Sun, Wenjun
Source :
Ceramics International. Nov2019, Vol. 45 Issue 16, p20656-20663. 8p.
Publication Year :
2019

Abstract

NaLa(MoO 4) 2 : Tb3+, Eu3+ phosphors were prepared via the hydrothermal method using sodium citrate as chelating agent, and different morphologies of the samples were obtained through the change of the Na 3 Cit molar ratio to rare earth ions. The NaLa(MoO 4) 2 : Tb3+, Eu3+ phosphors' structure, morphology, and temperature sensing performance were investigated using XRD (X-ray diffraction) and FE-SEM (Field Emission Scanning Electron Microscope) as well as temperature-dependent emission spectra. The XRD demonstrated that all the materials are body-centered tetragonal phase. The FE-SEM results show that a dosage of sodium citrate could control the NaLa(MoO 4) 2 : Tb3+, Eu3+ phosphors' morphology. On the basis of the temperature-dependent emission spectra, the FIR (Fluorescence Intensity Ratio) of Eu3+ and Tb3+ in all the samples changed with the temperature and could represent the temperature. Furthermore, the phosphors' sensitivity increased with the value of Cit3−/Re3+. Simultaneously, observed from the CIE (Commission International del'Eclairage) chromaticity coordinates, the range of the samples' luminescence color variation expanded with the Cit3−/Re3+ increases. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
02728842
Volume :
45
Issue :
16
Database :
Academic Search Index
Journal :
Ceramics International
Publication Type :
Academic Journal
Accession number :
138437971
Full Text :
https://doi.org/10.1016/j.ceramint.2019.07.048