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Synthetic and structural investigations of bis(N-alkyl-benzoselenadiazolium) cations.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 9/7/2019, Vol. 48 Issue 33, p12541-12548. 8p. - Publication Year :
- 2019
-
Abstract
- The synthesis, and spectroscopic and structural characterization of bridged dicationic derivatives of benzo-2,1,3-selenadiazoles are reported. The chloride salt of [H4C6NSeN–CH2–CH2–NSeNC6H4]2+ crystallizes forming a macrocyclic structure in which two cations are bridged by Se⋯Cl chalcogen bonds (ChBs), with a third chloride at the centre of the macrocycle. The structure of [1,2-(H4C6NSeN)2-C6H10]Cl2 consists of two selenadiazolium cations linked by a chiral cyclohexane and capped by Se⋯Cl ChBs. Tetrafluoroborate salts of a xylene bridge crystallize in two pseudopolymorphs in which the cations form Se⋯F ChBs in an anti- or syn-conformation. The triflate salt of ethylene-bridged cations dimerizes through the formation of the [Se–N]2 supramolecular synthon with Se⋯O ChBs capping the second selenium atom. In contrast, [H4C6NSeN–CH2–CH2–CH2–NSeNC6H4](CF3SO3)2 only forms Se⋯O ChBs. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CATIONS
*CYCLOHEXANE
*XYLENE
*SELENIUM
*CHLORIDES
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 48
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 138145085
- Full Text :
- https://doi.org/10.1039/c9dt02311a