Back to Search
Start Over
Reactions of hydrazones and hydrazides with Lewis acidic boranes.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 9/7/2019, Vol. 48 Issue 33, p12391-12395. 5p. - Publication Year :
- 2019
-
Abstract
- The reaction of (diphenylmethylene)hydrazone or 1,4-bis-hydrazone-ylidene(phenylmethyl)benzene with Lewis acidic boranes B(2,4,6-F3C6H2)3 or B(3,4,5-F3C6H2)3 generates the Lewis acid–base adducts. Alternatively, when (9H-fluoren-9-ylidene)hydrazone is employed several products were isolated including 1,2-di(9H-fluoren-9-ylidene)hydrazone, the 2 : 1 borane adduct of NH2–NH2 and the 1-(diarylboraneyl)-2-(9H-fluoren-9-ylidene)hydrazone in which one ArH group has been eliminated. The benzhydrazide starting material also initially gives an adduct when reacted with Lewis acidic boranes which upon heating eliminates ArH generating a CON2B heterocycle. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BORANES
*HYDRAZIDES
*CHEMICAL adducts
*BENZENE
*CARBORANES
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 48
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 138145065
- Full Text :
- https://doi.org/10.1039/c9dt01359h