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Synthesis and Characterization of Azine‐[5]Helicene Hybrids.
- Source :
-
European Journal of Organic Chemistry . 8/15/2019, Vol. 2019 Issue 30, p4879-4890. 12p. - Publication Year :
- 2019
-
Abstract
- Novel azine‐helicene hybrids (pyridine‐, pyrazine‐ and quinoxaline‐fused along the central ring [5]helicenes) have been prepared in good overall yields through a five‐step synthetic sequence. Commercially available 2,3‐dihaloazines were used as starting materials. To discern the effect of merging an azine moiety within a helical skeleton, the X‐ray structures, UV/Vis absorption spectra, cathodic and anodic electrochemistry of the helicene hybrids were investigated and compared to that of the parent [5]helicene. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ABSORPTION spectra
*ELECTROCHEMISTRY
*HELICAL structure
*SKELETON
*X-rays
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2019
- Issue :
- 30
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 138088371
- Full Text :
- https://doi.org/10.1002/ejoc.201900818