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Poly(piperizinamide) with copper ion composite membranes: Application for mitigation of Hexaconazole from water and combat microbial contamination.
- Source :
-
Journal of Hazardous Materials . Aug2019, Vol. 376, p102-111. 10p. - Publication Year :
- 2019
-
Abstract
- • Tailor-made Thin film Poly(piperizinamide) Composite membrane including copper moiety. • Selectivity in bivalent- monovalent salt depends on the sequence of reagents during interfacial polymerization. • Separation behavior of mono and disaccharides for all the membranes. • Separation behavior of Hexaconazole in different water matrices. • Development of antibacterial property related to E. Coli and Bacillus subtilis. Thin film Poly(piperazine-amide) composite membranes using sequential interfacial polymerization with tuning by Cu2+ have brought significant findings in it. The hydrophobicity is relatively enhanced for the copper containing membranes. The membrane in which copper solution is applied prior to piperizine (Memb-III) exhibits higher hydrophobicity where as membrane (Memb-II) in which copper solution is applied following piperizine, possesses higher roughness compared to other two. Filtration experiments in terms of salts, mono/disaccharides and hexaconazole indicate that modified membranes are of different behaviours according to their sequence of preparative methods. Memb-III has shown lower SO 4 =/Cl− selectivity compared to Memb-II (i.e. 3.92), though they are in different range. The unmodified membrane (Memb-I) exhibits SO 4 =/Cl− selectivity 3.23 is in the same scale of Memb-III (2.27). Memb-III exhibits higher hexaconazole separation (91.5%) compared to Memb-II (i.e. 53.9%). The flux decline follows the order: field water > tap water > deionized water. The copper incorporated membrane (Memb-II) has shown a low flux decline compared to Memb-III as well as Memb-I. The antibacterial properties towards E. Coli and Bacillus subtilis are well reflected. The copper containing membranes have promising antibacterial properties and follows the order Memb-II > Memb-III > Memb-I. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03043894
- Volume :
- 376
- Database :
- Academic Search Index
- Journal :
- Journal of Hazardous Materials
- Publication Type :
- Academic Journal
- Accession number :
- 136728982
- Full Text :
- https://doi.org/10.1016/j.jhazmat.2019.05.026