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Towards a hexa-branched [7]rotaxane from a [3]rotaxane via a [2+2+2] alkyne cyclotrimerization process.
- Source :
-
Chemical Communications . 3/25/2019, Vol. 55 Issue 24, p3525-3528. 4p. - Publication Year :
- 2019
-
Abstract
- A facile synthesis methodology to obtain a crown ether-based hexa-branched [7]rotaxane, has been achieved by using Co-catalyzed [2+2+2] alkyne cyclotrimerization from a [3]rotaxane. The [2+2+2] alkyne cyclotrimerization process, which requires only 10 mol% of Co2(CO)8 as a catalyst and affords an efficient production of target rotaxanes, represents a new strategy for the construction of highly complicated dendritic rotaxanes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ROTAXANES
*CONSTRUCTION
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 135429496
- Full Text :
- https://doi.org/10.1039/c9cc00363k