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Preparation of polypyrrole-decorated MnO2/reduced graphene oxide in the presence of multi-walled carbon nanotubes composite for high performance asymmetric supercapacitors.
- Source :
-
Physica B . Mar2019, Vol. 556, p66-74. 9p. - Publication Year :
- 2019
-
Abstract
- Abstract The present work demonstrates the preparation of polypyrrole-decorated MnO 2 /rGO by oxidative polymerization method as well as in the presence of CNTs composites. The as-prepared nanocomposites are investigated by XRD, ATR-IR, Raman, TGA, and TEM techniques. Results illustrate polypyrrole with spherical nanoparticles covering the surface of MnO 2 /rGO and CNTs in which CNTs are intercalated between MnO 2 /rGO layers (Py@MnG2). In the meantime, the electrochemical performances for the obtained samples are investigated by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and electrochemical impedance spectroscopy (EIS) experiments at 2 M KCl aqueous electrolyte. Owing to the presence of CNTs as well as the synergistic effect between polypyrrole and MnO 2 /rGO layers, the electrochemical performance of Py@MnG2 shows high specific capacitance of 295.83 F g−1 in a three-electrode system. The asymmetric supercapacitor (ASC) is assembled with Py@MnG2 and microwave exfoliated graphite oxide (MrGO) as positive and negative electrode material respectively. The as-fabricated ASC device exhibits a high energy density of 11.22 Wh Kg−1 and power density of 807.67 W kg−1 at 1 A g−1 in the potential window of 0–1.6 V. Moreover, the ASC device shows good cycling stability (78.42%) after 1000 cycles at 200 mV s−1. Highlight • A novel polypyrrole decorated MnO 2 /rGO in the presence of CNTs composite is prepared. • The as-prepared composite shows a high specific capacitance of 295.83 F g−1 in three-electrode system. • The assembled ASC exhibits a high energy density of 11.22 Wh Kg−1 at 1 A g−1. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09214526
- Volume :
- 556
- Database :
- Academic Search Index
- Journal :
- Physica B
- Publication Type :
- Academic Journal
- Accession number :
- 134549972
- Full Text :
- https://doi.org/10.1016/j.physb.2018.11.070