Isolation of lignocelluloses from the spent liquor of thermomechanical pulping process with fly ash and cationic polymer.

Abstract In this work, fly ash (FA) and polydiallyldimethylammonium chloride (PDADMAC) were utilized to treat the spent liquor (SL) of thermomechanical pulping (TMP) process in an effort to remove its lignocelluloses. The incorporation of PDADMAC into the system reduced the dosage of FA required for achieving acceptable lignocellulose removals. The maximum lignocellulose removals of 81%, 78%, 56%, 53% and 97% were achieved for lignin, hemicellulose, COD, BOD, and turbidity via treating SL with 100 g/L of FA at 25 °C for 60 min and subsequently treating with 100 mg/L of PDADMAC at 25 °C for 30 min, respectively. Comparing the two-step processes, FA pretreatment with PDADMAC post treatment was more effective than the two step process of PDADMAC pretreatment and FA post treatment. In this case, the FA pretreatment generated metal-organic complexes, and the addition of PDADMAC facilitated the formation of large flocs that could be separated from the system readily. A one stage process of combined PDADMAC and FA was less effective than the two-stage process of FA and PDADMAC treatments in removing lignocelluloses from SL. Graphical abstract Image 1 Highlights • Spent liquor of mechanical pulping process contains lignocelluloses. • Fly ash and cationic polymer were used for treating spent liquor. • A two-step treatment of fly ash and cationic polymer was very effective. • A one step treatment of fly ash or cationic polymer was not as effective. [ABSTRACT FROM AUTHOR]