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Diastereoselective Synthesis of Cyclic sp3-Enriched cis-ß-Alkoxysulfonyl Chlorides.
- Source :
-
Synthesis . 2019, Vol. 51 Issue 4, p948-958. 11p. - Publication Year :
- 2019
-
Abstract
- A three-step synthesis of ß-alkoxy-substituted alicyclic sulfonyl chlorides from cyclic alkenes and alcohols is reported. The scope of the method was studied for a range of the substrates with various steric and electronic properties. The title compounds were obtained on a hundred-gram scale in up to 52% overall yield scale as single cis-diastereomers. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CHLORIDES
*ALKENES
*ALCOHOL
*DIASTEREOISOMERS
*STERIC factor (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 51
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 134440714
- Full Text :
- https://doi.org/10.1055/s-0037-1611277