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Physical and dielectric properties of poly(vinylidene fluoride)/polybenzimidazole functionalized graphene nanocomposites.
- Source :
-
Journal of Polymer Science Part B: Polymer Physics . Feb2019, Vol. 57 Issue 4, p189-201. 13p. - Publication Year :
- 2019
-
Abstract
- Polymer‐based nanocomposites with good dielectric behavior have engrossed research devotion because of their distinctive benefits in electronic applications. An in situ synthetic process for the polybenzimidazole functionalized graphene oxide (GBI) and its nanocomposite with poly(vinylidene fluoride) (PVDF) is described. GBI shows good dispersion in the bulk PVDF matrix implying a strong interaction of polybenzimidazole with PVDF as evident from morphological and FTIR studies. A gradual increment of GBI in PVDF increases its piezoelectric β‐polymorph formation with a maximum of 73% for 10 wt % GBI in PVDF (GBF10) which also exhibits highest thermal stability. An exhaustive study of frequency dependent electrical properties of GBF10 indicates significantly higher dielectric constant (61), low dielectric loss (0.42), and low AC conductivity value of 1.17 × 10−10 S/cm at 100 Hz which are the key properties of a suitable capacitor. GBF10 also shows hydrophobic behavior (water uptake 2.89%) and low swelling ratio (1.143), providing an opportunity to use the composite film in fuel cell application. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019, 57, 189–201 Covalently functionalized graphene oxide with polybenzimidazole (GBI) shows homogenous dispersion in poly(vinylidene fluoride)(PVDF), and the composite exhibits 73% piezoelectric β‐polymorph formation for 10 wt % GBI in PVDF (GBF10). It shows significantly higher dielectric constant (61), low dielectric loss (0.42), and a low AC conductivity of 1.17 × 10−10 S/cm at 100 Hz appropriate for a capacitor. It also shows hydrophobic behavior (water uptake 2.89%) and low swelling ratio (1.143), providing an opportunity to use the composite film in fuel cell applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08876266
- Volume :
- 57
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Journal of Polymer Science Part B: Polymer Physics
- Publication Type :
- Academic Journal
- Accession number :
- 133850481
- Full Text :
- https://doi.org/10.1002/polb.24771