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Semiclassical Moyal dynamics.

Authors :
Shen, Yifan
Wang, Linjun
Source :
Journal of Chemical Physics. 12/28/2018, Vol. 149 Issue 24, pN.PAG-N.PAG. 8p. 4 Graphs.
Publication Year :
2018

Abstract

We present a semiclassical Moyal dynamics (SMD) method based on the phase space formulation of quantum dynamics. In contrast to the quantized Hamiltonian dynamics approach by Prezhdo et al. using the Heisenberg equation of motion, SMD adopts the Moyal equation of motion to derive the time evolution of expectation values and uses an auxiliary phase space distribution technique to systematically terminate the coupled equations of motion. Thereby, tedious derivation of commutators is essentially not required, and semiclassical dynamics of arbitrary orders can be realized. The appealing simplicity, flexibility, and reliability of SMD are demonstrated in three representative model systems with strong quantum effects. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
149
Issue :
24
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
133810022
Full Text :
https://doi.org/10.1063/1.5067005