The experimental study on the influence of crown ethers and glycols on the mutual solubility of lithium bromide in water.

Abstract In this paper, the continuation of our work on searching for anti-crystallization additives to the aqueous solution of lithium bromide is presented. This type of research is important from the viewpoint of absorption refrigeration technology to improve the performance of the efficiency of refrigeration equipment. In this study, three crown ethers: 12-crown-4, 15-crown-5, and 18-crown-6 as well as the glycols: ethylene glycol, diethylene glycol, triethylene glycol and glycerol were investigated as anti-crystallization additives for {LiBr (1) + water (2)} system, conventionally used as a working pair in absorption refrigeration technology. For this purpose, the solubility of lithium bromide in water has been determined in the presence of the organic additive. The solubility measurements have been carried out using a dynamic method at a wide temperature and composition range for different (additive to LiBr) initial mass fraction from w 2 0 = 0.1, 0.2 and 0.3. From experimental SLE data, the comparison range of the liquid state for tested systems at the absorber's working temperature was determined and compared to those from conventional (LiBr + water) system. Further measurements of vapor – liquid equilibria will be performed to select the best anti-crystallization additive. Highlights • Crown ethers and glycols have been investigated as an anti-crystallization additive for (LiBr + water) system. • The experimental data on solubility of {LiBr (1) + additive (2) + water (3)} at a wide temperature and composition range were presented. • Based on the SLE data anty-crystallization additive was chosen. [ABSTRACT FROM AUTHOR]