γ-FeOOH graphene polyacrylamide carbonized aerogel as air-cathode in electro-Fenton process for enhanced degradation of sulfamethoxazole.

Graphical abstract Highlight • A novel GPCA aerogel was fabricated to enhance SMX degradation in neutral E-Fenton. • γ-FeOOH was synthesized in situ into the carbonized aerogel framework. • Catalytic stability of GPCA-EF was greatly enhanced compared with traditional CF-EF. • Three possible pathways of SMX in GPCA-EF system was given. Abstract Novel γ-FeOOH graphene polyacrylamide carbonized aerogel (γ-FeOOH GPCA) was used as the cathode in neutral electro-Fenton (EF) process to achieve degradation and mineralization of sulfamethoxazole (SMX). γ-FeOOH GPCA cathode was fabricated by a multiple-phase carbonization method, leading to a good conductivity (26.37 Sm−1 with 7.5 mg mL−1 GO) and high electrochemically active surface area (EASA). An in situ synthesis method of γ-FeOOH was accomplished to distribute the catalyst uniformly and firmly into the carbonized aerogel framework. Two electron reduction could take place at the cathode, H 2 O 2 and Fe2+ can be generated at GPCA cathode efficiently. A 5-batch comparative assessment between GPCA-EF and CF-EF process exhibited the distinguished catalytic stability of GPCA cathode with a total organic carbon (TOC) removal efficiency of 89.8 ± 0.8%, 89.1 ± 0.9% and 84.7 ± 1.1% at the last 3 batches, respectively, versus 61.2 ± 1.2, 60.9 ± 1.1 and 59.4 ± 0.9% by CF cathode. This carbonized aerogel cathode demonstrated a great potential for the EF process to remove organic pollutants in water at neutral pH. [ABSTRACT FROM AUTHOR]