Back to Search
Start Over
Integration of Lanthanide–Transition‐Metal Clusters onto CdS Surfaces for Photocatalytic Hydrogen Evolution.
- Source :
-
Angewandte Chemie . Dec2018, Vol. 130 Issue 51, p17038-17042. 5p. - Publication Year :
- 2018
-
Abstract
- Heterometallic lanthanide–transition‐metal (4f–3d) clusters with well‐defined crystal structures integrate multiple metal centers and provide a platform for achieving synergistic catalytic effects. Herein, we present a strategy for enhanced hydrogen evolution by loading atomically precise 4f–3d clusters Ln52Ni56 on a CdS photoabsorber surface. Interestingly, some Ni2+ ions in the clusters Ln52Ni56 were exchanged by the Cd2+ to form Ln52Ni56−xCdx/CdS composites. Photocatalytic studies show that the efficient synergistic multipath charge separation and transfer from CdS to the Eu52Ni56−xCdx cluster enable high visible‐light‐driven hydrogen evolution at 25 353 μmol h−1 g−1. This work provides the strategy to design highly active photocatalytic hydrogen evolution catalysts by assembling heterometallic 4f–3d clusters on semiconductor materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 130
- Issue :
- 51
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 133500287
- Full Text :
- https://doi.org/10.1002/ange.201811211