Metal–Organic Frameworks and Their Derived Materials as Electrocatalysts and Photocatalysts for CO2 Reduction: Progress, Challenges, and Perspectives.

Excessive CO2 emission due to a large amount of fossil fuel utilization has become a widespread concern, which causes both environmental and energy problems. To solve these issues, electrocatalytic and photocatalytic reduction of CO2 to produce value‐added chemicals have gained immense attention. Recently, metal–organic frameworks (MOFs) and their derived materials with high specific surface areas, controllable pore structures, and tunable chemical properties exhibit promising performance among the reported catalytic materials for CO2 conversion. This review describes the recent advances on the rational design and synthesis of MOF‐based electrocatalysts and photocatalysts for CO2 reduction. The importance of the catalytic processes is highlighted, followed by systematic understanding of MOF‐based catalysts for CO2 reduction through electrochemical and photochemical approaches. Special emphasis of this review is to introduce basic catalyst design strategies and synthesis methods as well as their resulting electrocatalysts and photocatalysts. One of the major goals is to elucidate the structures and properties that link to their catalytic activity, selectivity, and stability towards to CO2 reduction. We also outline the challenges in this research area and propose the potential strategies for the rational design and synthesis of high‐performance catalysts. Due to the controllable pore size distribution, high specific surface area, and the tunable properties, metal–organic framework (MOF)‐based electrocatalysts and photocatalysts have been recognized as promising candidates for CO2 reduction to value‐added chemicals. In this review recent advances are discussed in detail and the challenges and future directions are outlined. [ABSTRACT FROM AUTHOR]