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Unusual rearrangement in the reaction of cyclopropanated cyclopentadienes with Et3Al/CH2I2 in CH2Cl2.
Unusual rearrangement in the reaction of cyclopropanated cyclopentadienes with Et3Al/CH2I2 in CH2Cl2.
- Source :
-
Synthetic Communications . 2018, Vol. 48 Issue 19, p2539-2544. 6p. 5 Diagrams. - Publication Year :
- 2018
-
Abstract
- The reaction of Et3Al/CH2I2 reagent with cyclopropanated spiro[2.4]hepta-4,6-diene and 6-substituted fulvenes in CH2Cl2 was found to lead to the selective formation of rearrangement products through sequential cyclopropyl-allyl rearrangement and cyclopropanation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00397911
- Volume :
- 48
- Issue :
- 19
- Database :
- Academic Search Index
- Journal :
- Synthetic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 133102561
- Full Text :
- https://doi.org/10.1080/00397911.2018.1511999