Recent advances in reactions between arynes and organosulfur compounds.

Graphical abstract Highlights • Reactions between arynes and organosulfurs are reviewed. • S(II), S(IV), and S(VI) organosulfurs have distinctive reactivities with arynes. • Various aromatic organosulfurs are now synthesizable via aryne intermediates. Abstract The recent progress made on transformations involving the reactions between aryne intermediates and organosulfur compounds has been reviewed. A wide variety of aromatic organosulfurs are now synthesizable by generating arynes in the presence of organosulfur compounds. Organosulfurs have distinctive reactivities with arynes, which depend on the sulfur atom's valence state, that is, S(II), S(IV), and S(VI), as well as the presence or absence of other intra- or intermolecular reactive moieties. These novel transformations have enabled the diversity-oriented synthesis of unique aromatic organosulfurs that were once difficult to prepare by the conventional methods, paving the way for the development of molecules that are beneficial across numerous disciplines, including pharmaceutical science and materials science. [ABSTRACT FROM AUTHOR]