Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming.

C‐saturated Pd0 nanoparticles with an extended phase boundary to ZrO2 evolve from a Pd0Zr0 precatalyst under CH4 dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO2 is efficiently activated at oxidic phase boundary sites and PdxC provides fast supply of C‐atoms toward the latter. ZrO2‐promoted methane dry reforming on PdxC: C‐saturated Pd0 nanoparticles with extended phase boundary to ZrO2 evolve from a Pd0Zr0 precatalyst under CH4 dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO2 is efficiently activated at oxidic phase boundary sites and PdxC provides fast supply of C‐atoms toward the latter. [ABSTRACT FROM AUTHOR]