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Entrapment of polysulfides by Al2O3 modified separator for high energy Li–S redox flow batteries.

Authors :
Yan, Dengxin
Huang, Yudai
Fan, Chengwei
Wang, Xingchao
Yan, Junfeng
Lin, He
Jia, Dianzeng
Zong, Jun
Wang, Wei
Wu, Guangming
Source :
Journal of Alloys & Compounds. Jan2019, Vol. 770, p1229-1236. 8p.
Publication Year :
2019

Abstract

Abstract Although the lithium–sulfur redox flow batteries (Li–S RFBs) are promising candidates for large-scale energy storage application because of outstanding solubility of long-chain polysulfides and low cost of sulfur. Their implementation has been impeded by multiple challenges, especially the dissolution of intermediate lithium polysulfide (Li 2 S X) species into the electrolyte. Here, Al 2 O 3 particles decorated polypropylene separator (PP-Al 2 O 3) was investigated. The results show that the thermal stability and the electrolyte wettability of the PP-Al 2 O 3 separator are improved obviously. When the PP-Al 2 O 3 separator is used for Li–S RFB, the cyclic stability and rate capability of the battery are enhanced. The PP-Al 2 O 3 separators are effective in improving the initial discharge capacity of Li–S RFBs from 27.5 to 91.5 mAh g−1 at 6.25 mA cm−2. The reason could be ascribed to that the polar Al 2 O 3 coating not only alleviates the shuttle effect by chemical interaction and physical barrier, but also facilitates Li-ion migration by favorable electrolyte wettability. In addition, theoretical calculations reveal that chemical bonds are formed between Al 2 O 3 and Li 2 S X. This work provides the rational design strategy for functional separators at cell scale to effective utilizing of active sulfur and retarding of polysulfides, which offers the possibility of high energy density Li–S RFBs with long cycling life. Highlights • Al 2 O 3 layer can enhance the thermal stability and the electrolyte wettability. • PP-Al 2 O 3 separator is used as a shuttle inhibitor for Li–S RFBs. • Li–S RFBs using PP-Al 2 O 3 separator show excellent electrochemical performance. • The results of XPS show that the Li–O is formed between the Li 2 S X and the Al 2 O 3. • DFT calculations reveal the interaction between Li 2 S X and Al 2 O 3. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09258388
Volume :
770
Database :
Academic Search Index
Journal :
Journal of Alloys & Compounds
Publication Type :
Academic Journal
Accession number :
132487578
Full Text :
https://doi.org/10.1016/j.jallcom.2018.08.230