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A Salen-based covalent organic polymer as highly selective and sensitive fluorescent sensor for detection of Al3+, Fe3+ and Cu2+ ions.
- Source :
-
Journal of Materials Science . Jan2019, Vol. 54 Issue 1, p851-861. 11p. 1 Black and White Photograph, 1 Diagram, 9 Graphs. - Publication Year :
- 2019
-
Abstract
- A novel covalent organic polymer (Salen-COP) based on Salen-type Schiff base was synthesized by one-pot protocol involving the self-condensation of 3-formyl-4-hydroxyphenylboronic acid and the subsequent aldehyde-amine condensation with benzene-1,2-diamine. The Salen-COP was characterized by 13C CP/MAS NMR, Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy and X-ray powder diffraction spectrometry analysis. The morphological features of Salen-COP were also analyzed using scanning electron microscopy. The Salen-COP exhibited the significant fluorescence enhancing for the sensing of Al3+, while the obtained polymer also exhibited the dramatic fluorescence quenching for the sensing of Fe3+ and Cu2+. The detection limits were calculated to be 0.248 µM for Salen-COP@Al3+, 0.545 µM for Salen-COP@Fe3+ and 0.140 µM for Salen-COP@Cu2+, respectively. Furthermore, the Salen-COP was founded to be a reversible chemosensor for Al3+, Fe3+ and Cu2+ ions, which provided a unique opportunity in the development of multi-response polymer-based sensors. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222461
- Volume :
- 54
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Materials Science
- Publication Type :
- Academic Journal
- Accession number :
- 132400510
- Full Text :
- https://doi.org/10.1007/s10853-018-2821-3