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K7{(BO3)Mn[B12O18(OH)6]} <f>·</f> H2O: first manganese borate based on covalently linked B12O18(OH)6 clusters and BO3 units via Mn2+ cations
- Source :
-
Inorganic Chemistry Communications . Jun2004, Vol. 7 Issue 6, p781-783. 3p. - Publication Year :
- 2004
-
Abstract
- A novel manganese oxyborate, K7{(BO3)[B12O18(OH)6]} <f>·</f> H2O (1), which is the first example showing the edge-sharing between boron and transition metal, has been solvothermally synthesized. The structure consists of [B12O20(OH)4] and [BO3] which are linked through unusual MnO5 polyhedron via vertexes and edges. This compound exhibits NLO properties and the intensity of the green light (frequency-doubled output: <f>λ=532</f> nm) produced by 1 is as large as that of KDP. [Copyright &y& Elsevier]
- Subjects :
- *MANGANESE
*BORON
*METALS
*LIGHT
Subjects
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 7
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 13237428
- Full Text :
- https://doi.org/10.1016/j.inoche.2004.04.015