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Carboallylation of electron-deficient alkenes by palladium/copper catalysis.

Authors :
Semba, Kazuhiko
Ohta, Naoki
Yano, Yuko
Nakao, Yoshiaki
Source :
Chemical Communications. 10/18/2018, Vol. 54 Issue 81, p11463-11466. 4p.
Publication Year :
2018

Abstract

A method for the carboallylation of electron-deficient alkenes with tetraorganosilicon reagents and allylic carbonates based on Pd/Cu catalysis has been developed. This method affords a wide range of structurally diverse carbon skeletons from readily available starting materials, and tolerates various functional groups. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*ALLYLATION kinetics
*ALKENES
*ELECTRON-deficient compounds
*CATALYSIS
*COPPER catalysts
*PALLADIUM catalysts
*CARBONATES

Details

Language :
English
ISSN :
13597345
Volume :
54
Issue :
81
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
132247900
Full Text :
https://doi.org/10.1039/c8cc06023a
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