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The effects of agglomerate on the piezoresistivity of conductive carbon nanotube/polyvinylidene fluoride composites.

Authors :
Zhang, Peng
Lei, Shiying
Fu, Wei
Niu, Jiajia
Liu, Gang
Qian, Junmin
Sun, Jun
Source :
Sensors & Actuators A: Physical. Oct2018, Vol. 281, p176-184. 9p.
Publication Year :
2018

Abstract

Highlights • This paper focuses on the strain sensitivity of electrical conductivity of MWCNT/ PVDF conductive polymer composite. • An optimal combination of ductility and piezoresistivity is found slightly above the electrical percolation threshold. • An improved model of piezoresistivity is established to explain the experimental measurements. Abstract Conductive polymer composites are prepared with a polyvinylidene fluoride (PVDF) matrix and multiwalled carbon nanotube (MWCNT) as filler. The mechanical properties, electrical conductivity and piezoresistivity of the composites are investigated as a function of MWCNT volume fraction. An optimal combination of ductility and piezoresistivity is found in the composite slightly above the electrical percolation threshold, showing a maximum fracture strain ∼ 4 times higher than the pure PVDF samples, as well as an outstanding sensitivity of piezoresistive response. Increasing further the MWCNT volume fraction leads to deterioration of both ductility and piezoresistivity. The effects of MWCNT content on piezoresistivity and fracture strain can be understood based on the microstructure observations. In particular, by incorporating two characteristic microstructural features identified in the materials, i.e., the filler random distribution and the filler agglomerate, into a simple statistical network model, the experimental measurements of piezoresistivity can be successfully fitted and understood in a semi-quantitative manner. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09244247
Volume :
281
Database :
Academic Search Index
Journal :
Sensors & Actuators A: Physical
Publication Type :
Academic Journal
Accession number :
132149081
Full Text :
https://doi.org/10.1016/j.sna.2018.08.037