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Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation.
- Source :
-
Angewandte Chemie . 10/1/2018, Vol. 130 Issue 40, p13450-13454. 5p. - Publication Year :
- 2018
-
Abstract
- Abstract: A silver‐promoted oxidative benzylic C−H trifluoromethoxylation has been reported for the first time. With trifluoromethyl arylsulfonate as the trifluoromethoxylation reagent, various arenes, having diverse functional groups, undergo trifluoromethoxylation of their benzylic C−H bonds to form trifluoromethyl ethers under mild reaction conditions. In addition, the trifluoromethoxylation and the fluorination of methyl groups of electron‐rich arenes have been achieved to prepare α‐fluorobenzyl trifluoromethyl ethers in one step. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 130
- Issue :
- 40
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 131977132
- Full Text :
- https://doi.org/10.1002/ange.201807144