A comprehensive review on the use of second generation TiO2 photocatalysts: Microorganism inactivation.

Abstract Photocatalytic disinfection practices have been applied for decades and attract current interest along with the developments in synthesis of novel photocatalysts. A survey based investigation was performed for elucidation of photocatalytic treatment details as well as disinfection mechanism of microorganisms. The present work brings significant information on the utilization of second generation TiO 2 photocatalysts for inactivation of microorganisms typically using E. coli as the model microorganism. Special interest was devoted to the role of organic matrix either generated during treatment or as a natural component. Studies on photocatalytic disinfection were extensively reviewed and evaluated with respect to basic operational parameters related to photocatalysis, and types and properties of microorganisms investigated. Degradation mechanism and behavior of microorganisms towards reactive oxygen species during disinfection and organic matrix effects were also addressed. For successful utilization and effective assessment of visible light active photocatalysts, standard protocols for disinfection activity testing have to be set. Further improvement of the efficiency of these materials would be promising for future applications in water treatment processes. Graphical abstract Image 1 Highlights • A survey on TiO 2 photocatalytic disinfection of microorganisms with special emphasis on E. coli. • Application of second generation-visible light active photocatalysts. • Evaluation of inactivation mechanism and organic matrix effect. • Information on successful utilization of visible light active photocatalysts. • Future interest is directed to the development of experimental protocols. [ABSTRACT FROM AUTHOR]