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The Synthesis and Crystal Structures of Two-Dimensional Coordination Polymers of Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5...

Authors :
Spichal, Zdenek
Necas, Marek
Pinkas, Jiri
Novosad, Josef
Source :
Inorganic Chemistry. 5/3/2004, Vol. 43 Issue 9, p2776-2778. 3p.
Publication Year :
2004

Abstract

Reactions of Pr(NO3)3 with Ph2P(O)—CH2CH2—P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 yielded layered network coordination polymers with bidentate ligands spanning the lanthanide atoms in a bridging fashion. The praseodymium cations with ‘spacer’ ligands form two-dimensional building blocks assembling into either square grid or herringbone network. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
9
Database :
Academic Search Index
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
13139399
Full Text :
https://doi.org/10.1021/ic0499648