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Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes.

Authors :
Jin, Weiwei
Wu, Mingchang
Xiong, Zhimin
Zhu, Gangguo
Source :
Chemical Communications. 7/21/2018, Vol. 54 Issue 57, p7924-7927. 4p.
Publication Year :
2018

Abstract

A visible-light induced three-component reaction of difluoroalkyl halides, unactivated alkenes, and alkynyl sulfones is described, providing a direct and general approach to the construction of synthetically valuable β-difluoroalkylated alkynes under room temperature conditions. This represents the first intermolecular alkynyl-difluoroalkylation of unactivated alkenes. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
54
Issue :
57
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
130672676
Full Text :
https://doi.org/10.1039/c8cc03105c